Rates of sulfonation of divinylbenzene-crosslinked polystyrene in dimethyl sulfoxide

Crosslinked Styrene/divinylbenzene Network Systems

Differences in properties of pure metaand pure para-divinylbenzene crosslinked polystyrene and their sulphonated products have been correlated with probable network structural differences. The para-divinylbenzene copolymerizes more slowly than does the meta isomer to give a crosslinked copolymer which swells less, sulphonates less rapidly, and, when sulphonated, gives an ion exchanger which has...

DFT study of dimers of dimethyl sulfoxide in gas phase

Density functional (DFT) calculations at M05-2x/aug-cc-pVDZ level were used to analyze the interactions between dimethyl sulfoxide (DMSO) dimers. The structures obtained have been analyzed with the Atoms in Molecules (AIMs) and Natural Bond Orbital (NBO) methodologies. Four minima were located on the potential energy surface of the dimers. Three types of interactions are observed, CH•••O, CH•••...

Clinical Considerations of Dimethyl Sulfoxide

Effects of Dimethyl Sulfoxide on Neuronal Response Characteristics in Deep Layers of Rat Barrel Cortex

Introduction: Dimethyl sulfoxide (DMSO) is a chemical often used as a solvent for waterinsoluble drugs. In this study, we evaluated the effect of intracerebroventricular (ICV) administration of DMSO on neural response characteristics (in 1200–1500 μm depth) of the rat barrel cortex. Methods: DMSO solution was prepared in 10% v/v concentration and injected into the later...

dft study of dimers of dimethyl sulfoxide in gas phase

density functional (dft) calculations at m05-2x/aug-cc-pvdz level were used to analyze the interactions between dimethyl sulfoxide (dmso) dimers. the structures obtained have been analyzed with the atoms in molecules (aims) and natural bond orbital (nbo) methodologies. four minima were located on the potential energy surface of the dimers. three types of interactions are observed, ch•••o, ch•••...